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The hydrolysis of acetals and ketals of cis- and trans-1,2-cyclohexanediol. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article.

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The α-deuterium secondary kinetic isotope effect upon the hydrolysis of 2-(p-nitrophenoxy)tetrahydropyran and its relationship to values for the solvolysis of secondary alkyl arenesulfonates and the enzyme-catalysed hydrolysis of acetals. General acid catalyzed acetal hydrolysis. Synthesis of glycoimmunogen Tn-Thr-PS A1 Find more information on the Altmetric Attention Score and how the score is calculated. General base catalysis of the addition of alcohols to 1-phenylethyl carbocations. Neighboring Carboxyl Group Participation in the Hydrolysis of Acetals. General-buffer catalysis of the reaction of N-(hydroxymethyl)benzamide: a new pathway for the aqueous reaction of carbinolamides.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Sokolov, G.E. Acetals: a new organocatalysis chemotype for one-pot enantioselective α-amination. Publication Date (Print): December 1, 1986. Note: Copper nitrate/acetic acid as an efficient synergistic catalytic system for the chemoselective tetrahydropyranylation of alcohols and phenols. Design of multi-phase dynamic chemical networks. Yinfeng He, Ruggero Foralosso, Gustavo F. Trindade, Alexander Ilchev, Laura Ruiz‐Cantu, Elizabeth A. Clark, Shaban Khaled, Richard J. M. Hague, Christopher J. Tuck, Felicity R. A. J.

Neighboring Carboxyl Group Participation in the Hydrolysis of Acetals. Cyclization of Esters of 2-Aminomethylbenzoic Acid to Phthalimidine. Note: North, D.C. Phillips, J.A. Secondary .alpha.-deuterium isotope effects for the cleavage of formaldehyde hemiacetals through concerted and specific-base-catalyzed pathways. Anu Koivula,, Laura Ruohonen,, Gerd Wohlfahrt,, Tapani Reinikainen,, Tuula T. Teeri,, Kathleen Piens,, Marc Claeyssens,, Martin Weber,, Andrea Vasella,, Dieter Becker,, Michael L. Sinnott,, Jin-yu Zou,, Gerard J. Kleywegt,, Michael Szardenings,, Jerry Ståhlberg, and. Linear Free Energy Relationships in Enzymology.

The solution was cooled to room temperature and poured into a saturated NaHCO3 solution (10 mL) and then extracted with diethyl ether (3 x 10 mL). Note: Comparison of the rates of acetal hydrolysis in the assembly with the rate of the reaction of unencapsulated substrates reveals rate accelerations of up to 980 over the background reaction for the substrate diethoxymethane. Raftery. Mechanisms of hydrolysis and rearrangements of epoxides. Johnson, A.C.T.

Am. The Methoxymethyl Carbenium Ion Problem.

SULFATED ZIRCONIA AS AN EFFICIENT CATALYST FOR TETRAHYDRO PYRANYLATION AND ACETALIZATION.

Chenrui Chen, Junjun Tan, Ming-Chien Hsieh, Ting Pan, Jay T. Goodwin, Anil K. Mehta, Martha A. Grover, David G. Lynn.
Struktur und reaktivität aliphatischer diazoverbindungen—VI. General acid catalyzed acetal hydrolysis. …

Your Mendeley pairing has expired. Raja Mohanrao, Aromal Asokan, Kana M. Sureshan. LITHIATION OF AROMATIC SYSTEMS. Get article recommendations from ACS based on references in your Mendeley library. SYNTHESIS OF Redox potentials for some pyrylium and thiapyrylium salts. General Base and General Acid Catalyzed Intramolecular Aminolysis of Esters. Minjie Shen, Hongda Cao, Megan L. Robertson. o How does a reaction change its mechanism? Amanda G. Mennenga, Amy L. Johnson, Richard W. Nagorski. Hydrolysis of acetals in presence of acids is the reversal of acetal formation. Chemischer Informationsdienst. In lieu of an abstract, this is the article's first page. Shiue-Shien Weng, Hsin-Chun Li, Teng-Mao Yang. Changes in rate-determining step and mechanism as a function of pH. Publication History. Diastereomer-Differentiating Hydrolysis of 1,3-Diol-Acetonides:  A Simplified Procedure for the Separation of syn- and anti-1,3-Diols. Hydrolysis and Solvolysis as Benign Routes for the End-of-Life Management of Thermoset Polymer Waste. Won Heui Lee, H. Maskill, Iain D. Menneer. Pore-Functionalized Nanoporous Materials Derived from Block Copolymers. 1H,13C and17O NMR spectral studies on monocyclic dioxolanes, dioxanes, dioxepanes and dioxocanes and cycloalkane-fused (5-8-membered) bicyclic 1,3-dioxolanes and 1,3-dioxanes. The active site of porcine-pancreatic alpha-amylase: Factors contributing to catalysis. Anwar Hussain, M. Yamasaki, J.E.

Min Wang, Zhi-Guo Song, Hong Gong, Heng Jiang. General base catalysis of the addition of alcohols to 1-phenylethyl carbocations.


Mechanisms of hydrolysis and rearrangements of epoxides. An acetal is a functional group (-COR) formed on condensation between an alcohol and a carbonyl compound. Electron-donating properties of oxygen vs. sulfur. https://doi.org/10.1007/s00706-008-0051-0, https://doi.org/10.1002/9780470122822.ch1, https://doi.org/10.1016/j.tetlet.2005.03.011, https://doi.org/10.1016/S0065-3160(05)40006-4, https://doi.org/10.1080/00304949709355199, https://doi.org/10.1080/00304949609458573, https://doi.org/10.1080/00304949609458574, https://doi.org/10.1016/0006-291X(81)90277-1, https://doi.org/10.1016/S0008-6215(00)85754-7, https://doi.org/10.1007/978-3-663-19723-2_8, https://doi.org/10.1007/978-1-4684-9978-0_11, https://doi.org/10.1016/B978-0-08-021197-8.50007-5, https://doi.org/10.1016/S0069-8040(08)70089-X, https://doi.org/10.1007/978-3-642-46314-3_3, https://doi.org/10.1016/S0065-3160(08)60340-8, https://doi.org/10.1016/0003-9861(73)90481-5, https://doi.org/10.1016/S0008-6215(00)85034-X, https://doi.org/10.1007/978-1-4615-8660-9_8, https://doi.org/10.1016/S1874-6047(08)60465-5, https://doi.org/10.1016/S0040-4020(01)98766-6, https://doi.org/10.1016/S0008-6215(00)80118-4. Find more information about Crossref citation counts. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. General acid catalysis of acetal, ketal, and ortho ester hydrolysis. Biochemical and Biophysical Research Communications. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Authors: Pluth, Michael D; Bergman, Robert G; Raymond, Kenneth N Publication Date: Wed Sep 24 00:00:00 EDT 2008 Research Org. Changes in rate-determining step and mechanism as a function of pH. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Transacetalation: a convenient, nonaqueous method for effecting the deprotection of isopropylidene and benzylidene derivatives of sugars. Hydrolysis of symmetrical and unsymmetrical 1,3-imidazolidines of p-dimethylaminocinnamaldehyde. Marisa Ciampini, Patrick Perlmutter, Keith Watson. General acid catalyzed acetal hydrolysis. Changes in rate-determining step and mechanism as a function of pH. Neighboring Carboxyl Group Participation in the Hydrolysis of Acetals.

Organic Preparations and Procedures International. Journal of the American ... Thomas H. Fife, R. Natarajan.

General acid catalyzed acetal hydrolysis. Position du proton dans l'état de transition. Monatshefte für Chemie - Chemical Monthly.

Hydrolysis of symmetrical and unsymmetrical 1,3-imidazolidines of p-dimethylaminocinnamaldehyde. General-buffer catalysis of the reaction of N-(hydroxymethyl)benzamide: a new pathway for the aqueous reaction of carbinolamides. Katalytische Antikörper als Sonden für die Evolution von Enzymen: Modellierung einer frühen Glycosidase. 2. Changes in Rate-Determining Step and Mechanism as a Function of pH.. Find more information on the Altmetric Attention Score and how the score is calculated. Find more information about Crossref citation counts. SOME MECHANISTIC STUDIES ON THE HYDROLYSIS OF ACETALS AND HEMIACETALS. Hanno C Erythropel, Sairam V Jabba, Tamara M DeWinter, Melissa Mendizabal, Paul T Anastas, Sven E Jordt, Julie B Zimmerman. Spirocyclic Acetal-Modified Dextran as a Flexible pH-Sensitive Solubility-Switching Material. It transforms the acetal to an aldehyde or a ketone. This article is cited by

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. V.V. Transition States for Hydrolysis of Acetals, Ketals, Glycosides, and Glycosylamines. Get article recommendations from ACS based on references in your Mendeley library. General acid catalysis of ketal hydrolysis. Transition-state effects in the divalent metal ion catalysis of acetal hydrolysis. Doron Shabat, Subhash C. Sinha, Jean-Louis Reymond, Ehud Keinan.

General-acid-catalyzed imidazolidine ring opening. North, D.C. Phillips, J.A. Organische Chemie, Your Mendeley pairing has expired. Find more information about Crossref citation counts. Cyclization of Esters of 2-Aminomethylbenzoic Acid to Phthalimidine. Find more information on the Altmetric Attention Score and how the score is calculated. TETRAHYDROPYRANYLOXY-DIRECTED The hydrolysis of acetals and ketals of cis- and trans-1,2-cyclohexanediol. The acetal formation mechanism is extremely similar; in fact, it’s the same exact thing but starting from the hemiacetal. Soc.

18 publications. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Annual Review of Chemical and Biomolecular Engineering. Changes in rate-determining step and mechanism as a function of pH. Johnson, A.C.T.

Min Wang, Zhiguo Song, Xin Wan, Shuang Zhao. Changes in rate-determining step and mechanism as a function of pH .

This article is cited by You have to login with your ACS ID befor you can login with your Mendeley account. General Base and General Acid Catalyzed Intramolecular Aminolysis of Esters. General acid catalyzed acetal hydrolysis.

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